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Improved Joining and Sealing for Thermoset Composite Pipes

The Non-Metallic Innovation Centre (NIC) is developing an innovative method of joining reinforced thermosetting resin (RTR) composite pipes that has the potential to replace an adhesive and a sealing gasket, contributing to a more reliable joining solution for the oil and gas (O&G) industry.

In the O&G industry, there is a huge opportunity for replacing traditional metallic pipes with non-metallic alternatives such as RTR composites, with the promise of significant cost savings achieved by eliminating corrosion. Greater deployment of RTR pipes can also contribute to availing more sustainable solutions with lower carbon emissions, considering the life-cycle carbon footprint of composite pipes compared to metallic pipes. O&G companies have invested a great deal of effort in deploying composite pipes (including RTR) for transporting hydrocarbons and other fluids, but they recognise that limitations have hindered further deployments. The NIC Foresight Review (NIC, 2019) has also concluded that one of the medium-term gaps in the industry is the development of new connections and sealing systems for large diameter (>16”) high-pressure (>1500 psi) applications.

The NIC, working with Saudi Aramco Technologies Company (SATC) and Future Pipe Industries (FPI), has begun a feasibility study into innovative joining solutions that will address the common issues currently limiting wider adoption of non-metallic pipes. The main issue with the current joints is the rigorous surface preparation required to ensure a good adhesive bond between the pipe ends - a process that must be carried out in the field, where quality is more difficult to control.

The proposed solution is to replace the adhesive with a thermoplastic welded solution. The main advantage of this approach is that layers of thermoplastic can be applied to the joining surfaces at the manufacturing stage, where strict quality control measures can be relied upon. Subsequent joining in the field would then not require any further preparation as the polymer welding process is much less sensitive to surface condition. The quality of the joints could therefore be guaranteed, significantly reducing the chance of failures in service.

Welding thermoset composites is, however, not straightforward, and depositing the thermoplastic layer on the surface of the thermoset has to be carried out in a way that not only provides sufficient adhesion strength, but is also compatible with 16-inch pipe diameters. The idea of using a thermoplastic joining interlayer has been successfully used to join aerospace thermoset composites by modifying the composite’s surface layers, adding thermoplastic fibres, fillers or particles to the matrix, creating a pseudo-thermoplastic interface. However, this approach is not practical (economical) for joining resin pipes for the O&G industry.

A recent TWI Core Research Programme (CRP) project (Flipo et al., 2019) successfully applied a polymer layer on to the surface of a continuous fibre thermoplastic composite using linear friction welding (LFW); a process originally developed for joining metals. Once coated, these parts were joined to each other using the linear friction welding technique. The resulting joints were found to have strength comparable to an adhesive, without any signs of damage to the underlying composite fibres.

The same approach was adopted by the NIC, after substituting the thermoplastic composite for samples of glass reinforced epoxy (GRE) thermoset laminates provided by FPI, comprising the same fibre/matrix system used in their WaviStrongTM RTR pipes. A series of welding operations was carried out using a variety of surface preparation processes, joint geometries and welding parameters to produce a number of polymer-coated thermoset laminates. These were then welded to each other to produce a series of lap-shear coupons. Similar joint configurations were produced using the same GRE laminates and the epoxy adhesive currently used by FPI in their adhesively bonded joining system.

Mechanical testing carried out on all the joined coupons showed that the welded joints could achieve almost the same strength as when the adhesive was used, demonstrating the potential for a welded joint to replace an adhesive. Considering the practicality of the proposed solution, linear friction welding can readily be adapted to a rotating friction configuration to apply the polymer onto the outside of the pipe ends and to the inside of a pipe coupler. Once in the field, any of the conventional welding processes could be used to complete the joining process.

Figure 1. Welded thermoset joint
Figure 1. Welded thermoset joint
Figure 2. RTR pipe manufacture (©Future Pipe Industries)
Figure 2. RTR pipe manufacture (©Future Pipe Industries)

The project is now at the stage where the feasibility of the process has clearly been demonstrated, albeit on flat coupons. Joint strengths achieved have almost matched those obtained from using adhesives, even after only a limited process evaluation. The next stage of the project is to design a practical joint configuration on a realistic pipe geometry and to demonstrate that similar performance advantages are carried over from flat to cylindrical geometries. Further testing will be required to demonstrate the long-term durability of the welded joints, and their performance after exposure to water and hydrocarbon fluids.

An additional opportunity that this joining solution offers is the potential for the polymer interlayer to act as a seal, replacing the adhesive and forming an electrofusion type thermoplastic welded pipe fitting. A thermoplastic with good chemical resistance was used in the current project; but many other polymers may be suitable, depending on the intended application.

Looking to wider environmental benefits, non-metallic pipes generate a lower carbon and energy footprint compared to conventional metallic pipes, with the potential to reduce the carbon intensity by as much as 60%, simply by replacing a carbon steel pipe with a non-metallic RTR version (Zubail et al., 2021). The improved environmental impact cannot be ignored, especially as the wider use of large diameter non-metallic pipes for applications such as a national hydrogen distribution network mean that RTRs could become a ‘backyard technology,’ with 5,700 km of new hydrogen pipelines planned by 2040 (Jens et al., 2021).

References

Flipo B., Worrall C., Clark P. and Greenwood J., 2020: ‘Linear Friction Welding of Carbon Fibre Reinforced Plastic’. TWI Industrial Member Report 1123/2019.

Jens J., Wang A., van der Leun K., Peters D. and Buseman M., 2021: ‘Extending the European Hydrogen Backbone. A European hydrogen infrastructure vision covering 21 countries’. Guidehouse, The Netherlands.

NIC, 2019: ‘Foresight Review - Application of Non-metallics in the Oil and Gas Industry’. Non-metallic Innovation Centre, Cambridge, UK.

Zubail A., Traidia A., Masulli M., Vatopoulos K., Villette T. and Taie I., 2021: ‘Carbon and energy footprint of nonmetallic composite pipes in onshore oil and gas flowlines’. Journal of Cleaner Production, 305 (2021) 126150.

Avatar Dr Chris Worrall Technology Fellow and Consultant – Polymer Composite Technologies

Chris is an expert in composite materials and a Consultant and Technology Fellow at TWI. His 35 year career covers: joining, mechanical behaviour, fire testing, finite element analysis, electromagnetic surface waves and metamaterials. Chris started his career in the oil and gas industry participating in the Marinetech North West project, and also spent 10 years working in Japan in the automotive, aerospace and energy sectors. He has presented guest lectures at Cambridge, Liverpool and Surrey University, and holds the position of ‘Engineer in Residence’ at Liverpool university. Recently, Chris has been supporting the Non-metallic Innovation Centre (NIC) in providing non-metallic solutions for the oil and gas industry.

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